|
HS Code |
581400 |
| Cas Number | 632-79-1 |
| Molecular Formula | C8Br4O3 |
| Molecular Weight | 511.6 g/mol |
| Appearance | White to off-white crystalline powder |
| Melting Point | 290-293°C |
| Solubility In Water | Insoluble |
| Density | 3.1 g/cm³ |
| Boiling Point | Decomposes before boiling |
| Odor | Odorless |
| Purity | Typically ≥ 98% |
| Chemical Name | Tetrabromophthalic anhydride |
| Synonyms | TBPA; 3,4,5,6-Tetrabromophthalic anhydride |
| Ec Number | 211-162-9 |
| Shelf Life | Stable under recommended storage conditions |
As an accredited Tetrabromophthalic Anhydride factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | A 500-gram amber glass bottle with a tightly sealed screw cap, labeled "Tetrabromophthalic Anhydride" and hazard warnings displayed. |
| Container Loading (20′ FCL) | 20′ FCL container loads 10 metric tons of Tetrabromophthalic Anhydride, packed in 25 kg bags, safely palletized for shipping. |
| Shipping | Tetrabromophthalic Anhydride should be shipped in tightly sealed containers, protected from moisture and incompatible substances. Store and transport in a cool, dry, well-ventilated area. Handle with appropriate PPE. Follow regulatory guidelines for hazardous materials. Ensure labeling and documentation comply with local and international chemical shipping regulations. |
| Storage | Tetrabromophthalic Anhydride should be stored in a tightly sealed container, in a cool, dry, well-ventilated area away from incompatible substances such as strong bases and oxidizers. Protect it from moisture and direct sunlight. Use appropriate labeling and ensure containers are non-reactive. Regularly check for signs of leakage or deterioration, and store following local regulations and chemical safety guidelines. |
| Shelf Life | Tetrabromophthalic Anhydride typically has a shelf life of at least 2 years when stored in a cool, dry, and sealed container. |
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Purity 98%: Tetrabromophthalic Anhydride with a purity of 98% is used in the formulation of epoxy resins, where it ensures high flame retardancy and thermal stability. Melting Point 300°C: Tetrabromophthalic Anhydride with a melting point of 300°C is used in high-temperature composites, where it enhances heat resistance and maintains structural integrity. Particle Size <10 µm: Tetrabromophthalic Anhydride with a particle size below 10 µm is used in plastic compounding, where it allows uniform dispersion for consistent flame retardant performance. Free Bromine Content <0.1%: Tetrabromophthalic Anhydride with free bromine content below 0.1% is used in polyester production, where it minimizes unwanted side reactions for product stability. Thermal Stability up to 280°C: Tetrabromophthalic Anhydride demonstrating thermal stability up to 280°C is used in wire and cable insulation, where it maintains non-flammability under prolonged exposure to heat. |
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Our journey with Tetrabromophthalic Anhydride began long before environmental regulations sharpened across the globe and well ahead of the spike in awareness about flame-retardant chemicals’ safety and efficiency. Every batch that leaves our factory reflects a decade’s worth of process refinements, conversations with end users, and lessons learned from feedback in the field. Over the years, we’ve watched the market shift from commodity brominated products toward high-purity, ultra-reliable ingredients that play well with evolving polymer requirements and meet strict compliance goals. Through all these changes, we’ve stayed responsive by refining our Tetrabromophthalic Anhydride process—eliminating the guesswork for our partners who care about fire resistance, long-term material stability, and regulatory acceptability.
Anyone walking the aisles of a modern polymer plant or electrical parts warehouse may not immediately recognize Tetrabromophthalic Anhydride, often identified by its model code TBPA or the chemical formula C8Br4O3. Yet this slightly sticky, off-white to pale yellow powder shapes how everyday products respond to fire. As a flame retardant, it’s found a secure foothold in unsaturated polyester resin systems, epoxy resins, and thermoplastic polyesters. When we first moved from general brominated flame retardants to this aromatic anhydride, we did so because its structure delivers two things at once: notable fire resistance and good compatibility with wide-ranging polymer systems. Unlike more primitive additives, the molecule anchors itself reliably into the final matrix, resisting migration and leaching—qualities directly observed during our own post-manufacture storage and long-term application testing.
Our standard TBPA features a bromine content that consistently measures between 67% and 69%. This high bromine loading anchors its flame-retardant capability, keeping dosage rates manageable even when aiming for strict V-0 ratings in UL94 testing. Moisture content and impurities define how well TBPA disperses and reacts in resins, and we've set our allowed moisture limits below 0.5%. Granule size and dustiness matter during processing; we control particle size so the powder integrates smoothly without plugging feed screws or caking in storage bins. Through direct feedback from customers running continuous production lines, we’ve honed the filtration and drying steps, making sure our TBPA keeps mixtures flowing, not clogging or bridging. Our typical color stays lighter than some imports, a difference some end users note when processing clear or lightly colored goods—fewer off shades, less need for optical brighteners or color correction.
We’ve finished countless comparative burn tests on panels, molded articles, and wire coatings, placing TBPA alongside other halogenated and non-halogenated flame retardants. Some older products—think Decabromodiphenyl Ether or Pentabromodiphenyl Oxide—release significant amounts of free bromine during formulation and service life, leading to odor, equipment corrosion, and environmental restrictions that only get tighter. In contrast, TBPA’s stable ring structure limits these emissions. The anhydride form also allows better reaction with polymer backbones. Formulators using our TBPA often see lower loss-on-ignition and longer retention of flame resistance, particularly after repeated heat cycling. The difference lies in how TBPA binds into the resin structure at a molecular level—so the flame-retardant effect remains strong over years of use and even in harsh operating environments.
Flame-retardant plastics are everywhere, but electrical and electronic industries see some of the most visible gains from TBPA’s use. Our customers manufacture circuit boards and electrical housings that must endure not only high voltages but also public-safety fire ratings. For instance, a well-known electrical enclosure producer tested our TBPA against a legacy additive, looking at both mechanical strength and post-burn charring. The TBPA-modified materials passed V-0 flame classifications with an improved smoothness of char and less tendency for dripping or smoke formation. Another partner mixing insulation for appliance wiring found that TBPA’s compatibility with polyester resins allowed higher additive loading without severe plasticizer loss or brittle finished cables. Our customers in the transport sector, particularly those producing seat cushions and interior panels, use TBPA to achieve compliance with stringent automotive and rail flammability standards. These aren’t just claims: every data point comes directly from feedback loops, third-party certifications, and side-by-side pilot-scale blending trials.
Work inside the lab has shown us that TBPA doesn’t work by simple dilution of polymer combustibility. Instead, its bromine atoms actively participate in interrupting the combustion process, forming a stable, insulating char that cuts heat transmission and oxygen exposure. Some non-halogenated agents, such as aluminum trihydrate or magnesium hydroxide, require high loadings to achieve similar results, which often impact the mechanical properties or weight of the final part. TBPA avoids this trade-off—less material, the same or greater level of fire protection. Moreover, TBPA stands out for its thermal stability. In contrast, low-melting brominated compounds can volatilize during molding or curing, exposing workers to fumes and causing process headaches. By experience, we notice fewer emissions at our plant’s vent stacks during campaigns running TBPA, and end-users also report less equipment fouling downstream.
Our product line includes two purity grades: the standard industrial grade and a higher-purity variant for applications needing especially low contamination—think sensitive electronics, aerospace, or situations where residual acid or metal ions could cause corrosion. We’ve invested heavily in closed-system filtration and computer-controlled crystallization units to push impurity levels down. Removing trace residuals isn’t just an academic exercise; one large molding customer found that tiny iron content, present in earlier lots of less-refined TBPA, catalyzed discoloration and affected resin curing. As scrutiny grows on every additive, moving from 98% to 99.5% purity has helped partners pass tougher regulatory reviews and minimized warranty returns tied to chemical instability. We also document our impurity profiles fully and regularly share up-to-date spectroscopic data—real-world transparency, not just a line in a brochure.
Running a chemical plant means grappling daily with environmental questions. TBPA, as a halogenated compound, gets plenty of attention. Over the years, we've responded by retooling our process: energy recovery from exothermic steps, hydrogen bromide capture and reuse, and real-time pollution monitoring. Unlike some legacy flame retardants, TBPA’s profile in waste water is more manageable. We've updated our purification to minimize by-products—no more seeing red or brown effluent after post-reaction wash cycles. In one initiative, scrubber upgrades allowed us to sharply reduce fugitive bromine, a move prompted not just by local law but by input from neighbors downwind of our stack. The precise chemistry of TBPA formation gives us a chance to mitigate impact from the start, rather than chasing environmental problems after the fact.
Anyone who’s handled fine powders knows the challenges: dust control, respiratory protection, and slip risk. With TBPA, particle size and static cling always test our housekeeping skills. We redesigned loading bays so air knives blow excess powder off bags before they leave the charging area. The TBPA blend’s relative bulk density has made it easier to automate dosing for our resin producers, reducing operator exposure. For the rare spill, our cleanup guidelines focus on minimizing airborne dust before anyone sweeps or vacuums. We share best practices with downstream users—the same PPE standards we apply here, from fitted respirators to dedicated change rooms, echo those recommended in our customer calls and training documents. Nothing substitutes for direct experience: lines that remain dust-free day after day owe their stability to countless incremental changes on the shop floor, not just engineered solutions.
Regulations in Europe, North America, and parts of Asia keep tightening permissible emissions of flame retardant chemicals, both during manufacture and end use. TBPA stands out against compounds like DecaBDE, now facing outright bans, while increasingly taking the spotlight in materials declared “BFR-compliant” or RoHS ready. Our compliance team works closely with third-party auditors to support reach registrations and environmental product declarations as required by automotive and electronics clients. Whether it’s China RoHS or the ECHA consultation process, real product samples and full traceable documentation allow us to guarantee consistency and avoid shipment delays. We’ve seen whole sectors pivot to new flame retardants only to face hidden component problems months down the line—by updating our TBPA constantly and building direct links to the labs overseeing regulatory certifications, we help customers stay ahead of these changes.
We don’t view TBPA as a one-size solution. Our team spends significant time in customer facilities—the smells, sights, and process quirks all inform what we ship out. In one example, a processor running sheet-molding compounds for automotive under-hood parts flagged a recurring haze issue. Working directly at their site, we traced the cause to incompatibility between batch-supplied TBPA and a specific crosslinking agent. After several trials, we tweaked granule size and drying cycle, resulting in haze-free, fully compliant panels. In another case, a maker of clear resin switches looked for a way to boost fire resistance without dulling transparency. TBPA, at the right loading, provided compliance with minimal color change, something we verified together using a side-by-side accelerated UV exposure test. It’s these technical partnerships, not stock-in-trade sales pitches, that set the tone for our daily work.
From inside our plant, TBPA runs present repeatability and reliability in both batch and continuous reactors. Reaction kinetics behave steadily due to well-characterized starting materials—no wild swings in exotherm rates or side-product formation. This predictability reduces unscheduled shutdowns and keeps conversion yields high, metrics we track on every lot log. Unlike some complex flame retardants with sensitive multi-step synthesis, TBPA formation lends itself to straightforward scale-up, minimizing the chance of batch failure. Less downtime directly translates into lower costs and more consistent deliveries. Looking down the process line, the purification and drying steps don’t require exotic, energy-intensive protocols. Efficient filtration avoids operator exposure while keeping waste volumes manageable. Our people on the floor appreciate reliable production as much as our customers—reliability means equipment uptime and fewer after-hours trouble calls.
Our experience tells us material handling issues shape customer results as much as what goes into the package. We pack TBPA in moisture-barrier bags lined with inert film, followed by robust drums. That keeps clumping and caking at bay, even if the warehouse gets humid in summer. Simple improvements to container design, like reinforced seals and easy-to-grip handles, cut down on wasted bags and workplace spills. We recommend storing TBPA away from strong oxidizers and acids—direct from experience, not just hazard labels—since even small leaks or residue can affect downstream quality. We teach customers with high-volume feed systems to calibrate gravimetric dosing before changeovers, reducing the chance of blockages or uneven mixing. Open lines for technical support allow us to troubleshoot application questions, whether related to batch settling or unexpected tinting in finished plastics. These day-to-day realities matter just as much as high-level chemical theory: every production gain reflects attention to practical steps.
End users often push for both cost containment and ever-higher performance. TBPA finds itself at the sweet spot for many electrical, transport, and industrial products where strict fire safety codes intersect with the need for processability. Electrical connectors, switch housings, lamp sockets, and appliance enclosures that depend on TBPA demonstrate stable flame resistance that lasts for years—even as heat, vibration, and ambient humidity fluctuate. Upholstery foams for trains and buses, treated with TBPA-loaded resins, meet transit fire codes while still maintaining resilience and colorfastness. We’ve seen our TBPA used in panels for construction, providing not only enhanced fire barriers but also supporting green building certifications through careful formulation. Feedback from the field highlights that parts rarely return for flame-out or spontaneous ignition issues—real approval from inspectors and end users, not just the approval from a checklist or a certification stamp.
Manufacturing Tetrabromophthalic Anhydride keeps us connected to new trends, from green chemistry and circular economy goals to life cycle analyses of additive impacts. Our R&D team regularly revisits processing parameters and works side by side with polymer scientists, striving for higher-purity preparations and lower environmental footprint. Each tweak gets verified at small pilot lots before scaling up: this year, a focus on finer particle size led to improved blendability and fewer agglomerates during customer blending trials. Our cross-functional teams—operations, technical support, logistics—bring “boots on the ground” knowledge, supporting our partners beyond a simple transactional relationship.
Every kilogram of TBPA that ships from our plant reflects countless hours of hands-on attention, manufacturer’s empathy with downstream users, and openness to feedback. Whether a customer needs a bag or a bulk container, field-tested product documentation or a fresh look at polymer compatibility, our team approaches every challenge with direct experience. The result remains not just a chemical, but a guarantee of reliability, formulated by those who know the journey of TBPA from raw feedstock to finished end-use. We see value not just in technical specs, but in building confidence that flame resistance and compliance can go hand in hand with efficient production and responsibility at every link in the supply chain.