Brominated Polystyrene

    • Product Name: Brominated Polystyrene
    • Chemical Name (IUPAC): Poly(1-bromo-4-ethenylbenzene)
    • CAS No.: 88497-56-7
    • Chemical Formula: (C8H7Br)n
    • Form/Physical State: White powder
    • Factroy Site: No. 85, Sanmu Road, Dushan Village, Guanlin Town, Yixing City, Jiangsu Province, China
    • Price Inquiry: sales3@ascent-chem.com
    • Manufacturer: Jiangsu Sanmu Group Co, Ltd.
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    Specifications

    HS Code

    368942

    Chemical Formula (C8H7Br)n
    Appearance white to off-white powder
    Bromine Content 50-70%
    Molecular Weight variable (polymeric)
    Melting Point 230-260°C
    Thermal Stability good, decomposition > 350°C
    Solubility In Water insoluble
    Solubility In Organic Solvents soluble in some organic solvents (e.g., chloroform, toluene)
    Flame Retardant Efficiency high
    Density 1.5-2.0 g/cm³
    Glass Transition Temperature 80-110°C
    Color white or pale yellow
    Odor odorless
    Halogen Content bromine
    Main Application flame retardant in plastics

    As an accredited Brominated Polystyrene factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Brominated Polystyrene, 25 kg, is securely packed in a sealed fiber drum with an inner polyethylene bag for moisture protection.
    Container Loading (20′ FCL) **Container Loading (20′ FCL) for Brominated Polystyrene:** Typically 16-18 metric tons packed in 25 kg bags, loaded on pallets, suitable for efficient sea freight transport.
    Shipping Brominated Polystyrene is shipped in tightly sealed, moisture-resistant containers or fiber drums, typically lined with polyethylene bags to prevent contamination and moisture absorption. The material should be stored and transported in cool, dry conditions away from strong oxidizing agents. Proper labeling and compliance with relevant local, national, or international transport regulations is required.
    Storage Brominated polystyrene should be stored in a cool, dry, and well-ventilated area, away from heat sources, open flames, and strong oxidizing agents. Keep the container tightly closed and clearly labeled to prevent contamination. Ensure the storage area is equipped with suitable fire suppression systems, and handle with appropriate personal protective equipment to avoid dust generation and inhalation.
    Shelf Life Brominated Polystyrene typically has a shelf life of at least 2 years when stored in a cool, dry, and well-sealed container.
    Application of Brominated Polystyrene

    Purity 98%: Brominated Polystyrene with 98% purity is used in electronic circuit board laminates, where it ensures enhanced thermal stability and flame resistance.

    Molecular Weight 70,000 g/mol: Brominated Polystyrene with a molecular weight of 70,000 g/mol is used in thermoplastic molding compounds, where it provides uniform dispersion and consistent mechanical properties.

    Melting Point 230°C: Brominated Polystyrene with a melting point of 230°C is used in high-performance wire and cable jacketing, where it offers reliable processing and improved fire safety.

    Bromine Content 67%: Brominated Polystyrene with 67% bromine content is used in engineering plastics, where it enables superior flame retardancy and compliance with UL94 V-0 standards.

    Particle Size <10 μm: Brominated Polystyrene with a particle size below 10 μm is used in specialty coatings, where it produces smooth surface finishes and efficient flame retardant distribution.

    Thermal Stability up to 330°C: Brominated Polystyrene with thermal stability up to 330°C is used in insulation foams, where it maintains fire-resistant properties during high-temperature processing.

    Viscosity 120 cps: Brominated Polystyrene with a viscosity of 120 cps is used in polymer blends and compounding, where it allows for easy incorporation and uniform material flow.

    Residual Monomer <0.1%: Brominated Polystyrene with residual monomer below 0.1% is used in sensitive electronic encapsulants, where it minimizes potential contamination and off-gassing.

    Bulk Density 0.45 g/cm³: Brominated Polystyrene with a bulk density of 0.45 g/cm³ is used in masterbatch concentrates, where it promotes ease of handling and precise dosing.

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    Certification & Compliance
    More Introduction

    Brominated Polystyrene: Value from Our Experience on the Production Floor

    A Look Behind Our Product: Brominated Polystyrene (BPS)

    Over many years working with high-performance plastics and flame retardants, we have learned that Brominated Polystyrene stands out for its stability and reliability. From the earliest production trials to each ton we ship today, every batch in our plant reflects a commitment to consistency in both chemistry and performance. Our role as a true producer, not a go-between or a packager of someone else’s work, gives us full control of the polymerization, bromination, and purification steps.

    Our BPS, often offered as both BPS-65 and BPS-70 grades, matches the evolving demand for materials that resist ignition and hold up in harsh process environments. We manufacture granules and powders, both with clearly defined, traceable ingredient lists and production histories. This transparency lets our partners troubleshoot with us if questions ever come up on application fit or processing behavior.

    What We’ve Learned About Brominated Polystyrene in Real Use

    Engineers who use our BPS in engineering plastics, electrical housings, cable insulation and circuit board laminates return to us with similar feedback. Unlike older brominated flame retardants, our material does not create toxic dioxins during normal processing, nor does it migrate or bloom over time. These are facts confirmed by both our own lot analysis and by thousands of downstream converters.

    Non-drip performance has become an expectation, not a bonus, in today’s polymer blends. Our experience shows that BPS resists migration even after repeated heat cycling, which helps our customers secure longer product warranties and pass stricter UL and V-0 standard testing without surprises. In cable compounds and glass-reinforced engineering resins, BPS disperses evenly and survives the high compounding temperatures that melt other flame retardants or break their chemical backbone.

    Specifications That Matter in Practice

    Most of our customers appreciate BPS-65 and BPS-70 for two main reasons: high thermal endurance and reliable bromine content. BPS-65 has about 65% bromine by weight and BPS-70 has around 70% bromine. We do not just aim for a label number; each batch passes titration and post-polymerization analysis in our lab. Without these checks, small variances in bromine content can throw off an entire production run, reduce flame retardancy, or even trip wire insulation tests.

    We keep impurities in check, striving for less than 0.5% volatiles and less than 500 ppm residual styrene monomer. We measure particle size distribution carefully on every lot, as too wide a distribution clogs feeders and causes uneven dosing in twin-screw extruders. Our investments in closed-system handling and packaging stem directly from hard experience: uncontrolled dusting is a safety hazard and leads to unnecessary material loss.

    Usage Across Diverse Applications

    We have seen our BPS perform in dozens of fields, but two routes dominate: as an additive flame retardant for high-temperature polymers and as a reactive intermediate in specialty laminates. One of the major applications remains in glass-filled polyamides, polyesters, and PET-based electrical components. BPS supports resin systems that must tolerate solder reflow and lead-free wave soldering temperatures without losing flame resistance. The material holds its polymer structure at 300°C and above, which means fewer surprises from charring or color shifts at the extruder or molding press.

    Another area where customers rely on our grade is in printed wiring boards (PWBs). Legacy flame retardants in these systems gave off corrosive off-gasses or caused delamination in multilayer electronics. BPS avoids these trouble spots, providing an inert, non-reactive backbone in epoxy and polyimide boards used for everything from smart appliances to automotive control modules.

    Manufacturers building appliance housings, connectors, insulation sheets and parts for mass transit appreciate BPS’s ease of integration. In single-screw or twin-screw compounding, our product feeds smoothly, flows well with both filled and unfilled resins, and maintains batch-to-batch consistency. Our partners often say that downtime due to dusty additives has gone down, not just by a small margin but enough to free up labor for more pressing challenges.

    Comparing BPS With Other Flame Retardants: What Decades Have Taught Us

    Business partners and technical leads often ask why Brominated Polystyrene takes preference over the more familiar decabromodiphenyl ether, tetrabromobisphenol A, or hexabromocyclododecane. Based on years of data, the answer is straightforward: BPS offers higher thermal stability, lower volatility, and fewer regulatory headaches in Europe, North America, or East Asia. Regulatory trends have left established but problematic flame retardants facing bans or phase-outs due to bioaccumulation and negative findings on endocrine disruption.

    Unlike the above, our BPS does not show persistence or the same potential for leaching in field tests or accelerated weathering studies. We have run our own series of high-temperature aging and extractables analyses, and the migration rates are barely detectable after standard use cycles. In direct side-by-side extrusion with antimony-trioxide, BPS wins out for toxicity concerns—partners looking to lower antimony use in sensitive or audit-prone markets rely on BPS as a bromine-only solution.

    Comparing with halogen-free retardants such as aluminum diethyl phosphinate or melamine derivatives, we recognize the push for safer chemistries. Yet customer feedback underlines a persistent fact: where tough UL 94 V-0 ratings at thin wall and at high process temperatures are non-negotiable, BPS outperforms and easily fits into existing production lines. Not everyone wants to deal with the hydration sensitivity, odor, or processing challenges of phosphinate or melamine cures, especially where color or impact strength matter.

    We have also tracked the reactivity of BPS in reactive extrusion or cross-linking systems. BPS remains inert, resisting breakdown in blends with polysulfones, polycarbonates, or liquid crystal polymers. Other bromines, such as TBBPA, may work as reactive monomers but complicate resin viscosity and cure rates.

    Supporting Reliable and Safe Production

    From dozens of on-site audits and customer scaling runs, we know that dust control and feeding uniformity top engineers’ checklists. Our granules and powders come in moisture-tight drums and bags, each sealed at the source with unique lot data. We have installed in-line metal detection and 100% visual inspection for each packaging line. These aren’t just theoretical measures—incidents of foreign matter or contamination nearly disappeared after we made the switch, saving time for both our partners and our own downstream operations.

    The process team continuously samples from each reactor and dryer load for bromine content, particle size, and color index. Customers indicate that consistency on simple things—such as free-flow in a volumetric feeder—counts just as much as advanced test results. Over the years, we saw that minimizing dust and fines not only eases housekeeping at our customer’s plants, but also leads to smoother pellet conveying and fewer unexpected downtime events.

    We support each shipment with full analytical records, not just summary certificates. This means any question—from regulatory authorities, internal auditors, or partners scaling to full production—gets a prompt fact-based response rather than guessed history or vendor deferral. Our goal since day one has been to own our product's story from monomer to shipment.

    Recycling and Environmental Considerations

    Recyclers and processors regularly ask about the environmental impact of BPS-based products. Our feedback is this: BPS does not appear in persistent organic pollutant lists, and our production is free of dioxin-forming processes. Downstream, waste handling follows standard practices for engineering plastics; incinerators equipped for brominated waste show emissions below threshold values for regulated compounds.

    Our investment in closed-loop water and solvent use keeps discharges nearly nil. Any off-grade material generated returns to our reactor for controlled re-bromination, cutting landfill to record lows. We have taken part in regional take-back schemes for off-spec electrical or automotive parts, and we support auditing of our own supply chain for compliance with RoHS, REACH, and local rules. Environmental Health and Safety teams also conduct regular workplace monitoring not only in our own units but at customer facilities who wish to verify safe dust levels or worker exposure.

    BPS-based products can be mechanically recycled in most polyamide and polyester resin streams, provided that sorting and shredding keeps contamination below agreed limits. A handful of partners shoot for more complicated chemical upcycling, but most value the inert backbone of BPS and simply grind and remold parts as needed.

    Technical Service: Lessons Learned From the Production Floor

    Most of our value as a producer comes from staying close to the factory floor. Plants running continuous compounding lines need fast answers, not just polite instructions. Our technical and plant teams link up directly with compounding specialists, offering dosage guidance, troubleshooting poor dispersion, and sharing side-by-side aging studies. We do not rely on templated recipes—our people have run every major screw profile and resin blend in our own test line, often with our clients on-site.

    If a converter faces unexpected plate-out, color change, or UL failure, our technical support looks at full histories: feeder calibration, resin shots, dryer logs, and real-time plant data. In more than a few cases, the answer has come from our own past experience—like tweaking residence times or feeding temperatures, or adjusting for variations in glass content or filler load.

    We keep our pilot plant running so visitors and partners can see blends and dosages tested in real time. Our sample archives run back years, allowing us to compare current performance not only against book specs but against real-world processing history.

    Economic Realities in Supply, Scale, and Pricing

    Raw monomers, energy cost, and bromine supply dictate the daily realities of BPS pricing and contracts. We buy bromine direct from primary sources and manage on-site inventory to buffer against logistic hiccups or sudden price swings. Sourcing from our own reactors rather than buying intermediates means we answer to no one else’s timeline or markup. We built our capacity for seasonal and annual contract volume swings to reduce risk for both our operation and our customers.

    Some traders or agents claim to handle supply disruptions better, but only a real manufacturer with a dedicated production line can pivot plant schedules or quickly qualify new resin combinations. We support partners scaling from pilot trials to full production by storing forecasted volume at our own site, releasing against monthly or quarterly call-offs, not first-come, first-served scatter-shot supply.

    Cost per kilo matters, but so does loss from run stoppages, rework, or scrap when additive quality veers off-target. Investing in product consistency helped both us and our partners escape more expensive supply chain headaches down the line. This is why, despite fierce competition and cheaper alternatives on the market, our consistent customers have stayed even through price cycles—they can plan and avoid the hidden costs of inferior product swaps and the pain of UL or customer returns.

    Safety, Handling, and Workforce Experience

    Anyone who has spent time on a production line knows that real handling issues—dust clouds, slip hazards, or static discharges—cause more lost hours than paper procedures ever address. We design our BPS granules to minimize fines and promote safe dispensing. Closed-system drum filling and anti-static bags have nearly eliminated plant incidents related to airborne particles. Training doesn't just go to compliance; our plant managers and shift leads conduct hands-on sessions with customer line operators to show best-practice setup for their specific lines.

    In our packing hall, we monitor for dust, shelf life, and mixing uniformity, cycling older stock or reserving “first in, first out” pallets for rush orders. These details often become make-or-break for partners running as little as a half-ton batch or as much as a rail car shipment. As we rotate our own staff through these jobs, small improvements keep appearing—from better sealing tape to sensor-aided drum lifts—because real experience, not just clipboard checks, catches what standard operating procedures can’t.

    Real World Challenges and Where We Go Next

    Every supplier can talk up textbook features, but long-term customers stay for solutions when things don’t go as planned. Over one stretch, a major partner faced a polymer supply outage and asked us to adapt BPS doses for a new, higher molecular weight resin. Regular suppliers had no answers, but we could match application needs with modified granule sizing and direct-to-extruder dosing. The faster feedback and willingness to share production data moved the project forward faster than outside consultants or an arm’s-length distributor.

    New regulations or material bans will keep changing the landscape. As flame retardant standards get tougher, the drive for more sustainable and non-halogenated products grows. We keep our development team connected both to the production floor and research labs, combining short-term adaptation with long-term product improvement. Batch-to-batch analysis lets us track incremental improvements in purity, stability, and cost, helping partners future-proof their designs even as requirements shift from local fire codes to international green chemistry rules.

    Our Commitment to Real Partnership

    Manufacturing and selling BPS means more than shipping a drum or a sack. From daily plant meetings to urgent troubleshooting calls, our job extends to supporting partners in actual production, not just the sales office. We base every improvement on production data, customer input, and process feedback. This attitude comes from living the process, running shifts on our own lines, and standing behind every lot we fill.

    As markets change and expectations rise, we see BPS not as a “one size fits all” answer, but as a product whose real value comes from hands-on knowledge and consistent care at each step, right from reacted monomer to safely shelved finished goods. Years of feedback, challenge, and process refinement taught us there’s no substitute for deep understanding of how products behave on real production lines with real people running them. Our entire approach grows from those lessons, and we commit to using every hour of that experience to support both the present and future needs of our customers.